佟振合

中国科学院院士、有机化学家

佟振合，1937年9月1日出生于山东梁山，有机化学家，中国科学院院士，中国科学院理化技术研究所研究员，学术委员会主任。

人物经历

1963年，佟振合毕业于中国科学技术大学高分子化学和物理系。

1963年09月—1974年04月，佟振合任中国科学技术大学化学系助理教授。

1974年04月—1979年09月，佟振合任中国科学院感光化学研究所助理研究员。

1979年09月—1983年09月，佟振合就读于美国哥伦比亚大学化学系，并获得博士学位。

1983年09月—1999年09月，佟振合先后任中国科学院感光化学研究所副研究员、研究员。

1999年09月，佟振合进入中国科学院理化技术研究所工作；同年当选为中国科学院院士。

2012年09月，佟振合加盟山东大学。

主要成就

科研成就

佟振合利用超分子体系作为微反应器，在高底物浓度条件下高选择性地合成大环化合物提出在烯烃光敏氧化中得到单一类型的氧化产物的新方法。提出疏脂性的概念并证明其存在。研究了用硬链段连接的给体－受体分子内远程电子转移和三重态能量传递，用光化学和光物理相结合的方法为通过“化学键”进行电子转移和能量传递提供了成功的例证。

据2020年2月山东师范大学官网显示，已在国内外核心刊物Acc. Chem. Res.、J. Am. Chem. Soc.等发表论文400余篇。多次应邀在国际学术会议上报告工作。

学术著作：

学术论文：

（1）Visible Light Irradiation of Acyl Oxime Esters and Styrenes Efficiently Constructs β‑Carbonyl Imides by a Scission and Four-Component Reassembly Process,Org. Lett.,2019-10,第6作者

（2）Benzyl C-O and C-N Bond Construction via C-C Bond Dissociation of Oxime Ester under Visible Light Irradiation,Eur. J. Org. Chem.,2019-08,第6作者

（3）Cobaloxime Catalysis: Selective Synthesis of Alkenylphosphine Oxides under Visible Light,J. Am. Chem. Soc,2019-08,第8作者

（4）Hand-in-hand Quantum Dot Assembly Sensitized Photocathode for Enhanced Photoelectrochemical Hydrogen Evolution,J. Mater. Chem. A,2019-07,第7作者

（5）Direct Arylation of Unactivated Alkanes with Heteroarenes by Visible-Light Catalysis,J. Org. Chem.,2019-07,第6作者

（6）Photoelectrochemical Cell for P–H/C–H Cross-coupling with Hydrogen Evolution,Chem. Commun.,2019-07,第7作者

（7）Regioselective Ortho Amination of an Aromatic C−H Bond by Trifluoroacetic Acid via Electrochemistry,Org. Lett.,2019-07,第7作者

（8）Efficient and Selective CO2 Reduction Integrated with Organic Synthesis by Solar Energy,Chem,2019-07,第10作者

（9）Semiconductor Quantum Dots: an Emerging Candidate for CO2 Photoreduction,Adv. Mater.,2019-07,第3作者

（10）Stiff-Stilbene Derivatives as New Bright Fluorophores with Aggregation-Induced Emission,Sci. China Chem.,2019-07,第5作者

（11）Visible Light Triggered Selective Intermolecular [2+2] Cycloaddition of Extended Enones: 2-Oxo-3-enoates and 2,4-Dien-1-ones with Olefins,J. Org. Chem.,2019-06,第7作者

（12）Quantum Dot Assembly for Light-Driven Multielectron Redox Reactions,Angew. Chem. Int. Ed.,2019-05,第2作者

（13）Photocatalytic C–C Bond Activation of Oxime Ester for Acyl Radical Generation and Application,Org. Lett.,2019-05,第4作者

（14）Activation of S—H and N—H Bonds to Synthesize Sulfinamides via Cross Coupling Hydrogen Evolution,Acta Chim. Sinica,,2019-04,第3作者

（15）Visible-Light-Induced Nanoparticle Assembly for Effective Hydrogen Photogeneration,ACS Sustainable Chem. Eng.,2019-03,第7作者

（16）Pure Organic Room Temperature Phosphorescence from Excited Dimers in Self-Assembled Nanoparticles under Visible and Near-Infrared Irradiation in Water,J. Am. Chem. Soc.,2019-03,第6作者

（17）Visible Light-Catalytic Dehydrogenation of Benzylic Alcohols to Carbonyl Compounds by Using an Eosin Y and Nickel–Thiolate Complex Dual Catalyst System,Green Chem.,2019-02,第5作者

（18）Catalytic Hydrogen Production Using A Cobalt Catalyst Bearing a Phosphinoamine Ligand,ChemPhotoChem,2019-02,第7作者

（19）Superhydrophilic Graphdiyne Accelerates Interfacial Mass/Electron Transportation to Boost Electrocatalytic and Photoelectrocatalytic Water Oxidation Activity,Adv. Funct. Mater.,2019-01,第10作者

（20）陈雅静,李旭兵,佟振合,吴骊珠.人工光合成制氢[J].化学进展,2019,31(01):38-49.

（21）Susceptible Surface Sulfide Regulates Catalytic Activity of CdSe Quantum Dots for Hydrogen Photogeneration,Adv. Mater.,2018-12,第10作者

（22）Construction of Cyclobutanes by Multicomponent Cascade Reactions in Homogeneous Solution through Visible-Light Catalysis,Chem. Eur. J.,2018-12,第6作者

（23）Chiral Inductions in Excited State Reactions: Photodimerization of Alkyl 2-Naphthoates as a Model,Photochem. Photobiol.,2018-07,第11作者

（24）To Construct Cyclobutanes by Multicomponent Cascade Reactions in Homogeneous Solution via Visible Light Catalysis,Chem. Eur. J.,2018,第6作者

（25）Chiral Inductions in Excited State Reactions: Photodimerization of Alkyl 2-Naphthoates as a Model,Photochemistry and Photobiology,2018,第11作者

（26）Chemo- and Regioselective Synthesis of Alkynyl Cyclobutanes by Visible Light Photocatalysis,Org. Lett.,2018,第7作者

（27）Photocatalytic Activation of Less Reactive Bonds and Their Functionalization via Hydrogen-Evolution Cross-Couplings,Acc. Chem. Res.,2018,第11作者

（28）Direct Synthesis of Sulfide Capped CdS and CdS/ZnS Colloidal Nanocrystals for Efficient Hydrogen Evolution under Visible Light Irradiation,J. Mater. Chem. A,2018,第8作者

（29）Three-Dimensional Graphene Networks with Abundant Sharp Edge Sites for Efficient Electrocatalytic Hydrogen Evolution,Angew. Chem. Int. Ed.,2018,第8作者

（30）Exceptional Catalytic Nature of Quantum Dots for Solar Hydrogen Evolution without External Cocatalysts,Adv. Funct. Mater.,2018,第8作者

（31）Luminescence-Tunable Polynorbornenes for Simultaneous Multicolor Imaging in Subcellular Organelles,Biomacromolecules,2018,第5作者

（32）Photocatalytic Hydrogen-Evolution Dimerization of Styrenes to Synthesize 1,2-Dihydro-1-arylnaphthalene Derivatives using Acr+-Mes and Cobaloxime Catalysts,Chin. J. Catal.,2018,第6作者

（33）Photocatalysis with Quantum Dots and Visible Light for Effective Organic Synthesis,Chem. Eur. J.,2018,第3作者

（34）Bio-inspired Cu4O4 “Cubane”: Effective Molecular Catalysts for Electrocatalytic Water Oxidation in Aqueous Solution,Angew. Chem. Int. Ed.,2018,第8作者

（35）Cu(II) Coordination Polymers with Nitrogen Catenation Ligands for Efficient Photocatalytic Water Oxidation,Chem. Commun.,2018,第4作者

（36）Metallic Co2C: A Promising Co-catalyst To Boost Photocatalytic Hydrogen Evolution of Colloidal Quantum Dots,ACS Catal.,2018,第8作者

（37）Self-Assembled Inorganic Clusters of Semiconducting Quantum Dots for Effective Solar Hydrogen Evolution,Chem. Commun.,2018,第9作者

（38）Surface Stoichiometry Manipulation Enhances Solar Hydrogen Evolution of CdSe Quantum Dots,J. Mater. Chem. A,2018,第7作者

（39）Recent Advances in Sensitized Photocathodes: From Molecular Dyes to Semiconducting Quantum Dots,Adv. Sci.,2018,第3作者

（40）Enhanced Charge Separation Efficiency Accelerates Hydrogen Evolution from Water of Carbon Nitride and 3,4,9,10-Perylenetetracarboxylic Dianhydride Composite Photocatalyst,ACS Appl. Mater. Interfaces,2018,第6作者

（41）Photo-Induced Reductive Cross-Coupling of Aldehydes, Ketones and Imines with Electron-Deficient Arenes to Construct Aryl Substituted Alcohols and Amines,Chin. J. Catal.,2018,第8作者

（42）Efficient Electronic Communication-Driven Photoinduced Charge-Separation in 2-Ureido-4[1H]-Pyrimidinone Quadruple Hydrogen-Bonded N,N-Dimethylaniline-Anthracene Assemblies,J. Photochem. Photobiol. A-Chem.,2018,第7作者

（43）Hole-Transfer-Layer Modification of Quantum Dot-Sensitized Photocathodes for Dramatically Enhanced Hydrogen Evolution,Part. Part. Syst. Charact.,2018,第5作者

（44）A Simple, Modular Synthesis of Bifunctional Peptide-Polynorbornenes for Apoptosis Induction and Fluorescence Imaging of Cancer Cells,Polym. Chem.,2018,第5作者

（45）Benzene C−H Etherification via Photocatalytic Hydrogen-Evolution Cross-Coupling Reaction,Org. Lett.,2017,第11作者

（46）Photocatalytic Hydrogen-Evolution Cross-Couplings: Benzene C−H Amination and Hydroxylation,J. Am. Chem. Soc.,2016,第11作者

（47）Biological Applications of Supramolecular Assemblies Designed for Excitation Energy Transfer,Chem. Rev.,2015,第11作者

（48）Synthesis of Diastereometrically Pure Cubane-Like Photodimers from 2,4-Pentanediyl-Bis-2-Naphthoates,Photochem. Photobiol. Sci.,2014,第11作者

（49）Enhancement of the Efficiency of Photocatalytic Reduction of Protons to Hydrogen via Molecular Assembly,Acc. Chem. Res.,2014,第11作者

（50）Stereoselective photodimerization of alkyl 3-alkoxyl-2-naphthoates,Tetrahedron Lett.,2011,第11作者

参与会议：

（1）Photocatalytic Activation of Inert Bonds and Their Functionalization via Hydrogen-Evolution Cross-Couplings 2019-10-17

（2）Photocatalytic Activation of Less Active Bonds and Their Functionalization via Hydrogen-Evolution Cross-Couplings 2019-05-24

（3）Photocatalytic Activation of Less Active Bonds and Their Functionalization via Hydrogen-Evolution Cross-Couplings 2018-12-17

（4）Visible Light Photocatalytic Activation of Inert Bonds and Their Functionalization via Hydrogen-Evolution Cross-Couplings 2018-07-10

（5）Photocatalytic Splitting of Water Based on Semiconducting Quantum Dots 2018-06-23

（6）Photocatalytic Activation of C-H Bonds: Hydrogen Evolution Cross-Coupling Reactions 2017-11-27

（7）Photocatalytic Dehydrogenative and Hydrogen-Evolution Cross-Couplig Reactions 中国化学会第十二届全国物理有机化学学术会议 2017-10-16

（8）Photocatalytic Splitting of Water into Molecular Hydrogen and Oxygen 2017-08-08

（9）可见光催化的放氢交叉偶联反应第六届化学与材料金砖论坛 2017-08-02

（10）Photocatalytic Dehydrogenative and Hydrogen-Evolution Cross-Couplig Reactions 一带一路国际绿色化学高端论坛 2017-07-14

（11）Photocatalytic Splitting of Water into Molecular Hydrogen and Oxygen 2017-01-03

（12）Photocatalytic Activation of C-H Bonds: Hydrogen Evolution Cross-Coupling Reactions 2016-12-04

（13）Photocatalytic Activation of C-H Bonds: Hydrogen-Evolution Cross-Coupling Reactions 第六届岭南有机化学论坛 2016-11-05

（14）Cross-Coupling Hydrogen Evolution Reactions Initiated by Photoinduced Electron Transfer 2015-12-15

（15）Molecular Assembly: Photocatalytic Splitting of Water into Hydrogen and Oxygen 2015-09-06

（16）Photocatalytic Reduction of Protons to Hydrogen 2015-08-17

（17）Photocatalytic Reduction of Protons to Hydrogen 2015-01-05

（18）Photocatalytic Reduction of Protons to Hydrogen 2014-11-14

（19）Chemical Transformations Initiated by Photoinduced Electron Transfer 2013-07-21

（20）超分子体系中的光诱导能量传递、电子转移和化学转换第九届全国物理有机化学学术会议佟振合 2011-11-03

（21）太阳能光催化制取氢气全国氢能大会佟振合 2011-10-15

人才培养

2010年9月19日，佟振合访问中国科学院长春应用化学研究所，为科研人员及研究生以《微反应器控制的有机光化学的选择性》为题作学术报告。他重点讲解了如何利用微反应器控制光化学反应的化学选择性、区域选择性和立体选择性这一提高化学反应选择性的重要方法和策略。

2018年11月11日上午，佟振合应邀在山东师范大学千佛山校区作了题为“Photocatalytic Activation of Inert Bonds and Their Functionalizatio via Dehydrogenative and Hydrogen-Evolution Cross-Coupling Reactions”的学术报告。他介绍了光化学反应方面的相关研究；详细解释了光化学反应中的交叉耦合反应；简要阐述了有机染料,有机金属配合物和半导体量子点作光催化剂的原理。

佟振合讲授《光化学绿色合成与催化》《人工光合作用与太阳能转换》《超分子化学》《有机光化学》课程。

荣誉表彰

参考资料

社会任职

人物评价

佟振合在利用微反应器控制光化学反应的选择性以及超分子体系中光诱导电子转移和能量传递的研究中做出了贡献。（亚洲及大洋洲光化学学会成就奖评）

佟振合有着渊博的学术知识、高尚的学识修养。（华东理工大学化学与分子工程学院评）

佟振合是中国光化学领域的主要学术带头人之一。（中国科学院理化技术研究所评）

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