夏永姚

复旦大学特聘教授

夏永姚（Yongyao Xia）复旦大学特聘教授，博士生导师；苏州大学兼职教授，浙江师范大学客座教授；杭州市钱江特聘专家。

人物生平

1965年8月出生于浙江余姚；1987年毕业于浙江师范大学化学系；1990年获吉林大学化学系电化学专业理学硕士学位；1990-1993年进入中国科学院长春应用化学研究所工作；1997年获日本佐贺大学能源-材料科学专业工学博士学位，同年留校任日本文部省教官讲师；1998年赴美国南卡罗来纳州化学工程系电化学中心做博士后研究员；1999-2001年在日本通产省大阪工业技术研究所做博士后研究员； 2001-2002年进入日立Maxell公司电池开发中心工作；2003年回复旦大学化学系工作。

研究方向

研究方向为物理化学和材料科学的交叉领域-功能材料电化学，当前主要的研究方向为（1）新型储能材料和储能技术的研究，包括液体锂离子电池、电化学电容器、染料敏化太阳能电池、燃料电池等；（2）无机-有机纳米复合材料在储能、催化、光致发光、物质分离及生物医药等领域中的应用；（3）功能材料的理论计算和模拟等研究。

成就

2003年回国后，主持包括多项863计划项目、国家自然科学基金重点基金、973计划项目子课题、上海市优秀学科带头人计划项目、国家自然科学基金面上项目，并与多家世界500强企业有合作研发项目。距今已发表SCI论文100余篇，包括Nature Chemistry, J. Am. Chem. Soc，Angew. Chem. Int. Edit.，Adv. Mater.，Adv. Fun. Mater，Chem. Mater., J. Electrochem. Soc.等，被国际学术刊物他引近2000次，单篇被他引近400次；授权和申请专利25项；参与著书3本。多项研究成果已经产业化。

先后获得的奖励有：2002年度日本电化学会志优秀论文奖，2005年入选教育部新世纪优秀人才计划，2009年国家自然科学基金委杰出青年基金获得者，上海市优秀学科带头人。

主要作品

1. Cui Wangjun, Li Feng, Liu Haijing, Wang Congxiao, Xia Yongyao. “Core-shell carbon-coated Cu6Sn5 prepared by in situ polymerization as a high-performance anode material for lithium-ion batteries“. Journal of Materials Chemistry. 19 (2009) 7202-7207. (Cover Page)

2. Liu Haijing, Cui Wangjun, Jin Linghua, Wang Congxiao, Xia Yongyao. “Preparation of three-dimensional ordered mesoporous carbon sphere arrays by a two-step templating route and their application for supercapacitors“. Journal of Materials Chemistry. 19 (2009) 3661-3667.

3. Liu Haijing, Jin Linghua, He Ping, Wang Congxiao, Xia Yongyao. “Direct synthesis of mesoporous carbon nanowires in nanotubes using MnO2 nanotubes as a template and their application in supercapacitors“. Chemical Communications. 44 (2009) 6813-6815.

4. Wang Xiaoming, Xia Yongyao. “FexC-C hybrid material as a support for Pt anode catalyst in direct formic acid fuel cell“. Electrochemistry Communications. 11 (2009) 28-30.

5. Yang Xinhui, He Ping, Xia Yongyao. “Preparation of mesocellular carbon foam and its application for lithium/oxygen battery“. Electrochemistry Communications. 11 (2009) 1127-1130.

6. Luo Jiayan, Chen Lijuan, Zhao Yujun, He Ping, Xia Yongyao. “The effect of oxygen vacancies on the structure and electrochemistry of LiTi2(PO4)3 for lithium-ion batteries: A combined experimental and theoretical study“. Journal of Power Sources. 194 (2009) 1075-1080.

7. Luo Jiayan, Xia Yongyao. “Electrochemical profile of an asymmetric supercapacitor using carbon-coated LiTi2(PO4)3 and active carbon electrodes“. Journal of Power Sources. 186 (2009) 224-227.

7. Wang Xiaoming, Xia Yongyao. “Synthesis, characterization and catalytic activity of an ultrafine Pd/C catalyst for formic acid electrooxidation“. Electrochimica Acta. 54 (2009) 7525-7530.

8. He Ping, Luo Jiayan, Yang Xinhui, Xia Yongyao. “Preparation and electrochemical profile of Li0.33MnO2 nanorods as cathode material for secondary lithium batteries“. Electrochimica Acta. 54 (2009) 7345-7349.

9. He Ping, Luo Jiayan, He Jianxin, Xia Yongyao. “Electrochemical Profile of Oxygen-Deficient LiMn2O4-delta in Aqueous Electrolyte“. Journal of the Electrochemical Society. 156 (2009) A209-A214.

11. Wu Wen, Wang Yonggang, Li Feng, Xia Yongyao. “Electrochemical Capacitance Performance of Ordered Mesoporous Co3O4 Synthesized by Template Method“. Chinese Acta Chimica Sinica. 67 (2009) 208-212.

12. Huan-Ming Xiong*, Yang Xu, Qing-Guang Ren, and Yong-Yao Xia* , “Stable Aqueous ZnO@Polyner Core#Shell Nanoparticles with Tunable Photoluminescence and Their Application in Cell Imaging”, Journal of the American Chemical Society ,130(24),7522-7523(2008)

13. Huan-Ming Xiong*, Xiao-Yan Guan,Ling-Hua Jin, Wenn-Wen Shen,Hao-Jie Lu*,and Yong-Yao Xia* , “Surfactant-Free Synthesis of SnO 2 @PMMA and TiO 2 @PMMA Core-Shell Nanobeads Designed for Peptide/Protein Enrichment and MALDI-TOF MS Analysis”, Angew.Chem.Int.Ed, 47 4204-4207(2008)

14. Yong-Gang Wang, Wen Wu, Liang Cheng, Ping He, Cong-Xiao Wang* and Yong-Yao Xia* , “A Polyaniline Intercalated Layered Manganese Oxide Nanocomposite Prepared by Inorganic/Organic Interface Reaction and Its High Electrochemical Performance for Li Storage”, Advanced. Materials , 2166 (2008)

15. Wang-jun Cui, Cong-xiao Wang, and Yong-yao Xia *, “ Highly ordered three-dimensional macroporous FePO 4 as cathode materials for lithium-ion batteries”, Electrochemistry Communications , 10 ( 10) ， 1587-1589 ， ( 2008)

16. Xiao-Ming Wang, Yong yao Xia* ”electrocatalytic performance of PdCo-C catalyst for formic acid oxidation”, Electrochemistry Communications ,10, 16444-1646 (2008)

17. Hai-jing Liu, Shou-hang Bo, Wang-jun Cui, Feng Li, Cong-xiao Wang*, and Yong-yao Xia* , “Nano-sized cobalt oxide/mesoporous carbon sphere composites as negative electrode material for lithium-ion batteries”, Electrochim. Acta, 53(22) ， 6497-6503(2008)

18. Guo-Xian Ma, Yong-Gang Wang, Cong-Xiao Wang*, Tian-Hong Lu*, Yong-Yao Xia*, “Hemoglobin immobilized on whisker-like carbon composites and its direct electrochemistry”, Electrochimica Acta 53,4738-4753(2008)

19. Jia-Yan Luo , Jin-Long Liu, Ping He, Yong-Yao Xia* ,“ A novel LiTi 2 (PO 4 ) 3 /MnO 2 hybrid supercapacitor in lithium sulfate aqueous electrolyte ”, Electrochimica Acta , 53, ( 28) , 8128-8133(2008)

20. Feng Li, Qing-Qing Zou, and Yong-Yao Xia *, “ CoO-loaded graphitable carbon hollow spheres as anode materials for lithium-ion battery” , Journal Power Sources ， 177(2), 546-552 (2008)

21. Hui-Qiao Li,Yong-Gang Wang,Cong-Xiao Wang, Yong-Yao Xia *“A competitive candidate material for aqueous supercapactiors ： High suface-area graphite” Journal Power Sources ， 185 （ 2008 ） 1557-1562

22. Jing-jun Zhang, Ping He,Yong-yao Xia* “Electrochemical kinetics study of Li-ion in Cu6Sn5 electrode of lithium batteries by PITT and EIS”, Journal of Electroanalytical Chemistry 624 ,161-166 (2008)

23. Ping He, Xiao Zhang, Yong-Gang Wang, Liang Cheng, and Yong-Yao Xia * , “Lithium-ion Intercalation Behavior of LiFePO 4 in Aqueous and Nonaqueous Electrolyte Solutions”, Journal of Electrochem. Society , 155(2), A144-A150 (2008)

24. Jia-Yan Luo, Huan-Ming Xiong and Yong-Yao Xia *, “LiMn 2 O 4 Nanorods, Nano-thorn Microspheres, and Hollow Nanospheres as Enhanced Cathode Materials of Lithium-ion Battery ”, Journal Physical Chemistry C , 112 (31), 12051–12057( 2008)

25. Jia-Yan Luo , Dan-Dan Zhou, Jin-Long Liu, Yongyao Xia *,“ Hybrid aqueous energy storage cells using activated carbon and lithium-ion intercalated compounds - IV. Possibility of using polymer gel electrolyte Source”, Journal of the Electrochemical Society , 155 ( 11) A789-A793 ( 2008)

26. Xiao Zhang, Cong-Xiao Wang*, Fu-You Li*, and Yong-Yao Xia *, “ A quasi-solid-state dye-sensitized solar cell based on porous polymer electrolyte membrane”, Journal of Photochemistry and Photobiology A: Chemistry, 194(1), 31-36 (2008)

27. Xiao Zhang, Jing-Jun Zhang, Yong-Yao Xia*, “Molecular design of coumarin dyes with high efficiency in dye-sensitized solar cells” , Journal of Photochemistry and Photobiology A:Chemistry , 194, 167-172 (2008)

28. Jia-Yan Luo and Yong-Yao Xia *, “ Aqueous Lithium-ion Battery LiTi 2 (PO 4 ) 3 /LiMn 2 O 4 with High Power and Energy Densities as well as Superior Cycling Stability”, Advanced Functional Materials , 17 (18), 3877-3884 (2007).

29. Yong Gang Wang, Liang Cheng, HuanMin Xiong, and Yong-Yao Xia*, “High electrocatalytic activity of oxygen reduction on an air electrode based on Mn 3 O 4 /mesoporous carbon”, Chemistry of Materials, 19, 2095 – 2101 ( 2007).

30. Jia-yan Luo, Yong-gang Wang, Huan-ming Xiong* and Yong-Yao Xia*, “Ordered Mesoporous Spinel LiMn 2 O 4 by a Soft-Chemical Process as a Cathode Material for Lithium-ion Batteries”, Chemistry of Materials, 19, 4791-4795 (2007).

31. Huan-Ming Xiong, Dong-Ping Xie, Xiao-Yan Guan, Yu-Jing Tan and Yong-Yao Xia*, “Ultrastable Blue-Emitting ZnO@Polymer Core-Shell Nanoparticles and Microspheres”, Journal of Materials Chemistry, 17 (24): 2490-2496 (2007). (Cover page).

32. Jing-jun Zhang, Xiao Zhang and Yong-Yao Xia * , “ Co doped Co x Cu 6- x Sn 5 Alloys as Negative Electrode Materials for Rechargeable Lithium Batteries”,Journal of Electrochem. Soc , 154(1), A7-A13 (2007).

33. Yong-gang Wang, Jia-yan Lou, Wen Wu, Cong-xiao Wang* and Yong-Yao Xia * , “ Hybrid Aqueous Energy Storage Cells Using Activated Carbon and Lithium-ion Intercalated Compounds. III. Capacity fading mechanism of Li Co 1/3 Ni 1/3 Mn 1/3 O 2 at different pH electrolyte solutions”, Journal of Electrochem. Society , 154 (3), A228-A234 (2007).

34. Liang Cheng, Xi-Li Li, Hai-Jing Liu, Huan-Ming Xiong, Ping-Wei Zhang and Yong-Yao Xia * , “ Carbon Coated Li 4 Ti 5 O 12 as a High Rate Electrode Material for Electrochemical Supercapacitors” , Journal of Electrochem. Society , 154 (7), A228-A234 (2007).

35. Huiqiao Li, Jiayan Luo, Xufeng Zhou, Chengzhong Yu* and Yong-Yao Xia*, “A new ordered mesoporous carbon with short pore length and its electrochemical performances in supercapacitor application” , Journal of Electrochem. Society , 154 (8), A731-A736 (2007).

36. Jia-Yan Luo, and Yong-Yao Xia*, “ Effect of Pore Structure on the Electrochemical Capacitive Performance of MnO 2 ”,Journal of Electrochem. Society , 154 (11), A987-A992 (2007).

37. Jiayan Luo, Liang Cheng and Yong-Yao Xia* , “ Single-Crystal LiMn 2 O 4 Hollow Nanospheres Electrode Material with Exellent Cycling Reversibility and Rate Capability”, Electrochemistry Communications, 9, 1404-1409 (2007).

38. Xiao Zhang, Jing-Jun Zhang, and Yong-Yao Xia*, “A comparative theoretical investigation of ruthenium dyes in dye-sensitized solar cells”, Journal of Photochemistry and Photobiology A: Chemistry, 185, 283-288 (2007).

39. Jia-Yan Luo, Xi-Li Li and Yong-Yao Xia * , “ Low-Temperature, Soft-Chemistry Method to Synthesize Highly Crystalline LiMn 2 O 4 Spinel Cathode Materials”, Electrochimica Acta, 52, 4525-4531 (2007)

40. Hui-qiao Li, Ying Zou, and Yong-Yao Xia*, “A study of nitroxide polyradical/activated carbon composite as the positive electrode material for electrochemical hybrid capacitor”, Electrochimica Acta, 52(5), 2153-2157 (2007) .

41. Jing-jun Zhang, Yi-min Zhang, Xiao Zhang and Yong-Yao Xia* , “ Ni x Cu 6- x Sn 5 Alloys as Negative Electrode Materials for Rechargeable Lithium Batteries”, Journal Power Sources ， 167, 171-177 (2007).

42. Guo-Xian Ma, Tian-Hong Lu* and Yong-Yao Xia * , “ Direct electrochemistry and bioelectrocatalysis o f hemoglobin immobilized on carbon black” , Journal of Bioelectrochemistry , 71, 180-185 (2007).

43.Xin-Hui Yang, Yong-Gang Wang, Huan-Ming Xiong* and Yong-Yao Xia ,* , “Interfacial Synthesis of Porous MnO 2 and Its Application in Electrochemical Capacitor”, Electrochimica Acta, 53, 752-757 (2007).

44. Hui-Qiao Li, Rui-Li Liu, Dong-Yuan Zhao* and Yong-Yao Xia*, “Electrochemical properties of an ordered mesoporous carbon prepared by direct tri-constituent co-assembly” , Carbons , 45, 2628–2635 (2007)

45. 马国仙，仲慧，陆天虹*，夏永姚 * ，“ 葡萄糖氧化酶在炭黑上的固定及直接电化学”，物理化学学报， 23, 1053-1058 (2007).

46. 李峰，刘海晶，王永刚，李会巧，夏永姚 * ， “Zn- 空气电池中二维与三维结构碳负载 Mn 3 O 4 的催化性能比较 ”, 高等学校化学学报 , 11 ， 2133-2137 (2007).

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