段春迎

张大煜学院院长

段春迎，男，博士，现任大连理工大学化工学院教授、博士生导师。

人物经历

教育经历

1989.9-1992.7南京大学无机化学博士

1986.9-1989.7吉林大学理论化学硕士

1982.9-1986.7吉林大学环境化学学士

工作经历

2006.3至今大连理工大学教授

2000.3-2006.3南京大学教授

1995.3-2000.3南京大学副教授

1992.9-1995.3南京大学讲师

社会兼职

大连理工大学化工与环境生命学部副部长

大连理工大学精细化工国家重点实验室

国家杰出青年科学基金获得者

国家自然科学基金委员会会评专家。

研究方向

主要从事功能配位化学研究，研究内容聚焦于金属-有机限域空间的可控组装、仿生识别与不对称催化等。

金属-有机限域空间的组装与分子识别

多重稳态晶态材料的制备与光磁耦合

复合功能框架结构的构建与仿生催

学术成果

科研项目

近年来，承担国家自然科学基金委员会重大、重点项目、国际合作重点项目，科技部 “973”课题等多项国家级项目。

二氧化碳催化转化与资源化利用, 大连市顶尖及领军人才项目, 2018/05/04, 进行

仿生识别与荧光传感创新团队, 科技部创新人才推进计划, 2016/05/17, 进行

应用于光还原二氧化碳的金属有机限域空间超分子体系的构筑, 国家自然科学基金, 2015/08/18, 进行

2005年度教育部新世纪优秀人才支持计划, 教育部新世纪优秀人才支持计划项目, 2005/12/31-2008/12/31, 完成

量子点细胞操纵器的设计和研究, 高等学校博士学科点专项科研基金项目, 2009/12/02-2012/12/31, 完成

针对代谢标志物的分子探针设计与合成, 973 计划项目, 2012/12/02-2018/08/13, 完成

晶态材料中自旋多重稳态的调控与磁构效关系研究, 国家自然科学基金, 2011/09/25, 完成

配位键导向的分子组装与荧光传感, 国家自然科学基金, 2010/09/25-2014/12/31, 完成

复杂混合价态无机固体材料的合成与性能, 国家自然科学基金, 2008/09/25-2011/12/31, 完成

染料分子功能调控, 国家自然科学基金, 2014/09/01, 进行

超分子化学与催化国际联合研究中心国合基地补助项目, 大连市科技创新专项, 2018/12/15, 进行

金属-有机大环酶模拟体系的可控组装与催化性能研究, 国家自然科学基金, 2018/08/16, 进行

科技部国际联合研究中心, 2019/03/25-2019/03/25, 进行

教育部“111引智计划”基地, 2019/03/25-2019/03/25, 进行

发表论文

在Nature Commun., J. Am. Chem. Soc., Angew. Chem. Int. Ed.等国际高水平刊物上发表SCI论文150余篇，论文被他引11000余次。

140. Yang Jiao, Jiqiu Yin, Haiyang He, Xiaojun Peng, Qianmiao Gao, and Chunying Duan*, Conformationally Induced Off-On Cell Membrane Chemosensor Targeting Receptor Protein-Tyrosine Kinases for in Vivo and in Vitro Fluorescence Imaging of Cancers, J. Am. Chem. Soc., 2018, 140, 5882–5885.

139. Zhiduo Chang, Xu Jing, Cheng He, Xin Liu, and Chunying Duan*, Silver Clusters as Robust Nodes and π−Activation Sites for the Construction of Heterogeneous Catalysts for the Cycloaddition of Propargylamines, ACS Catal., 2018, 8, 1384–139.

138. Linlin Yang, Xu Jing, Bowen An, Cheng He,* Yang Yang and Chunying Duan*, Binding of anions in triply interlocked coordination catenanes and dynamic allostery for dehalogenation reactions, Chem. Sci., 2018, 9, 1050–1057.

137. Hao Yu, Jing Wang, Xiangyang Guo, Rong Zhang, Cheng He*, and Chunying Duan*, Diversity of metal–organic macrocycles assembled from carbazole based ligands with different lengths, Dalton Trans., 2018, 47, 4040–4044.

136. Liang Zhao, Jianwei Wei, Jing Zhang, Cheng He,* and Chunying Duan*, Encapsulation of a Quinhydrone Cofactor in the Inner Pocket of Cobalt Triangular Prisms: Combined Light-Driven Reduction of Protons and Hydrogenation of Nitrobenzene, Angew. Chem. Int. Ed., 2017, 56, 15284–15288.

135. Xu Jing, Yang Yang, Cheng He,* Zhiduo Chang, Joost N. H. Reek,* and Chunying Duan*, Control of Redox Events by Dye Encapsulation Applied to LightDriven Splitting of Hydrogen Sulfide, Angew. Chem. Int. Ed., 2017, 56, 11759 –11763.

134. Liang Zhao, Jianwei Wei, Junhua Lu, Cheng He,* and Chunying Duan*, Renewable Molecular Flasks with NADH Models: Combination of Light-Driven Proton Reduction and Biomimetic Hydrogenation of Benzoxazinones, Angew. Chem. Int. Ed., 2017, 129, 8818–8822.

133. Bo Qi, Xiangyang Guo, Yunyi Gao, Dong Li, Jiancheng Luo, Hui Li, Seyed Ali Eghtesadi, Cheng He, Chunying Duan,* and Tianbo Liu*, Strong Co-Ion Effect via Cation-π Interaction on the Self-Assembly of Metal-Organic Cationic Macrocycles, J. Am. Chem. Soc., 2017, 139, 12020–12026.

132. Zhen Zhou, Cheng He, Lu Yang, Yefei Wang, Tao Liu, and Chunying Duan*, Alkyne Activation by a Porous Silver Coordination Polymer for Heterogeneous Catalysis of Carbon Dioxide Cycloaddition, ACS Catal., 2017, 7, 2248–2256.

131. Bo Qi, Tiexin Zhang,* Mochen Li, Cheng He and Chunying Duan*, Highly shape- and regio-selective peroxy–trifluoromethylation of styrene by metal–organic framework Cu3(BTC)2, Catal. Sci. Technol., 2017, 7, 5872–5881.

130. Yang Jiao, Xing Liu, Lu Zhou, Haiyang He, Peng Zhou, Chunying Duan*, A schiff-base dual emission ratiometric fluorescent chemosensor for Hg2 ions and its application in cellular imaging, Sensors and Actuators B, 2017, 247, 950–956.

129. Lu Yang, Liang Zhao, Zhen Zhou, Cheng He*, Hui Sun and Chunying Duan*,A thiourea-functionalized metal–organic macrocycle for the catalysis of Michael additions and prominent size-selective effect, Dalton Trans., 2017, 46, 4086–4092.

128. Yang Jiao, Lu Zhou, Haiyang He, Jiqiu Yin, Chunying Duan*, A new fluorescent chemosensor for recognition of Hg2ions based on a coumarin derivative, Talanta, 2017, 162, 403–407.

127. Liang Zhao, Jianwei Wei, Feili Zhang, Cheng He, Sijia Zheng and Chunying Duan*, Redox-active copper triangles as an enzymatic molecular flask for light-driven hydrogen production, RSC Adv., 2017, 7, 48989–48993.

126. Xiangyang Guo, Le Zeng, Zhe Wang, Tiexin Zhang, Cheng He and Chunying Duan*, Photocatalytic copper-catalyzed azide–alkyne cycloaddition click reaction with Cu(II) coordination polymer, RSC Adv., 2017, 7, 52907–52913.

125. Cuiping Wang, Zhiqiang Zhang,* Kui Liu, Jingbo Yan, Tiexin Zhang, Gonghao Lu, Qingtao Meng, Haijun Chi and Chunying Duan*, Copper-catalyzed synthesis of indolyl diketones via C–H oxidationdiacylation of indoles with arylglyoxal hydrates, Org. Biomol. Chem., 2017, 15, 6185–6193.

124. Le Zeng, Tao Liu, Cheng He, Dongying Shi, Feili Zhang, and Chunying Duan*, Organized Aggregation Makes Insoluble Perylene Diimide Efficient for the Reduction of Aryl Halides via Consecutive Visible LightInduced Electron-Transfer Processes, J. Am. Chem. Soc., 2016, 138, 3958–3961.

123. Le Zeng, Xiangyang Guo, Cheng He, and Chunying Duan*, Metal–Organic Frameworks: Versatile Materials for Heterogeneous Photocatalysis, ACS Catal., 2016, 6, 7935–7947.

122. Xiangyang Guo, Zhen Zhou, Cong Chen, Junfeng Bai, Cheng He, and Chunying Duan*, New rht-Type Metal–Organic Frameworks Decorated with Acylamide Groups for Efficient Carbon Dioxide Capture and Chemical Fixation from Raw Power Plant Flue Gas, ACS Appl. Mater. Interfaces., 2016, 8, 31746–31756.

121. Zhizhi Gu, Liyong Chen,* Binhua Duan, Qiong Luo, Jing Liu and Chunying Duan*, Synthesis of AuUiO-66(NH2) structures by small molecule-assisted nucleation for plasmonenhanced photocatalytic activity, Chem. Commun., 2016, 52, 116–119.

120. Dongying Shi, Cheng He, Wenlong Sun, Zheng Ming, Changgong Meng and Chunying Duan*, A photosensitizing decatungstate-based MOF as heterogeneous photocatalyst for the selective C–H alkylation of aliphatic nitriles, Chem. Commun., 2016, 52, 4714–4717.

119. Liyong Chen,* Binhua Duan, Qiong Luo, Zhizhi Gu, Jing Liu and Chunying Duan*, Facet-dependent catalytic activity of ZIF-8 nanocubes and rhombic dodecahedra based on tracing substrate diffusion in pores by SERS: a case study for surface catalysis of MOFs, Catal. Sci. Technol., 2016, 6, 1616–1620.

118. Pengyan Wu, Xiangyang Guo, Linjuan Cheng, Cheng He,* Jian Wang, and Chunying Duan*, Photoactive Metal−Organic Framework and Its Film for Light-Driven Hydrogen Production and Carbon Dioxide Reduction, Inorg. Chem., 2016, 55, 8153–8159.

117. Qiong Luo, Liyong Chen,* Binhua Duan, Zhizhi Gu, Jing Liu, Meiling Xu and Chunying Duan*, Porous N-doped graphitic carbon assembled onedimensional hollow structures as high performance electrocatalysts for ORR, RSC Adv., 2016, 6, 12467–12471.

116. Dongying Shi, Le Zeng, Zheng Ming, Cheng He, Changgong Meng and Chunying Duan*, A breathing MOF: direct crystallographic observation of the site-selective C(sp3)–H functionalization, RSC Adv., 2016, 6, 51936–51940.

115. Guangjie He*, Qingtao Meng, Xiuwen Zhao, Cheng He, Peng Zhou, Chunying Duan*, A new copper(II) selective fluorescence probe based on naphthalimide: Synthesis, mechanism and application in living cells, Inorg. Chem. Commun., 2016, 65, 28–31.

114. Xu Jing, Cheng He, Yang Yang, and Chunying Duan*, A Metal-Organic Tetrahedron as a Redox Vehicle to Encapsulate Organic Dyes for Photocatalytic Proton Reduction, J. Am. Chem. Soc., 2015, 137, 3967–3974.

113. Zhen Zhou, Cheng He, Jinghai Xiu, Lu Yang, and Chunying Duan*, Metal-Organic Polymers Containing Discrete Single-Walled Nanotube as a Heterogeneous Catalyst for the Cycloaddition of Carbon Dioxide to Epoxides, J. Am. Chem. Soc., 2015, 137, 15066–15069.

112. Dongying Shi, Cheng He, Bo Qi, Cong Chen, Jingyang Niu and Chunying Duan*, Merging of the photocatalysis and copper catalysis in metal–organic frameworks for oxidative C–C bond formation, Chem. Sci., 2015, 6, 1035–1042.

111. Jing Zhang, Cheng He, Chunying Duan*, Cerium-based metal–organic tetrahedron for selective sensing of ribonucleosides through the cooperation of hydrogen bonding interaction, Inorg. Chem. Commun., 2015, 54, 41–44.

110. Liyong Chen,* Yan Peng, Hong Wang, Zhizhi Gua and Chunying Duan*, Synthesis of AuZIF-8 single- or multi-core–shell structures for photocatalysis, Chem. Commun., 2014, 50, 8651–8654.

109. Liang Zhao, Yulu Chu, Cheng He and Chunying Duan*, Fluorescent detection of RDX within DHPA-containing metal–organic polyhedra, Chem. Commun., 2014, 50, 3467–3469.

108. Yang Jiao, Jian Wang, Pengyan Wu, Liang Zhao, Cheng He, Jing Zhang, and Chunying Duan*, Cerium-Based M4L4 Tetrahedra as Molecular Flasks for Selective Reaction Prompting and Luminescent Reaction Tracing, Chem. Eur. J., 2014, 20, 2224–2231.

107. Liang Zhao, Yang Liu, Cheng He,* Jian Wang and Chunying Duan*, Coordination-driven nanosized lanthanide 'Molecular Lanterns' as luminescent chemosensors for the selective sensing of magnesium ions, Dalton Trans., 2014, 43, 335–433.

106. Jichuan Kong, Cheng He, Xiaolin Zhang, Qingtao Meng, Chunying Duan*, Rhodamine based colorimetric and fluorescent probe for recognition of nucleoside polyphosphates through multi-hydrogen bond, Dyes and Pigments., 2014, 101, 254–260.

105. Wenting Zhu, Cheng He, Xiao Wu, Chunying Duan*, “Click” post-synthetic modification of metal-organic frameworks for asymmetric aldol catalysis, Inorg. Chem. Commun., 2014, 39, 83–85.

104. Yang Jiao, Cheng He, Chun-Ying Duan*, M4L4 cerium cages assembled from ligands with lower symmetry as a molecular flask, Inorg. Chem. Commun., 2014, 39, 147–150.

103. Jing Zhang, Cheng He, Chunying Duan*, Self-assembled cerium-based metal–organic tetrahedrons for selective recognition of natural saccharides, Inorg. Chem. Commun., 2014, 49, 140–142.

102. Qiuxia Han, Cheng He, Min Zhao, Bo Qi, Jingyang Niu, and Chunying Duan*, Engineering Chiral Polyoxometalate Hybrid Metal-Organic Frameworks for Asymmetric Dihydroxylation of Olefins, J. Am. Chem. Soc., 2013, 135, 10186–10189.

101. Cheng He, Jian Wang, Liang Zhao, Tao Liu, Jing Zhang and Chunying Duan*, A photoactive basket-like meta–organic tetragon worked as an enzymatic molecular flask for light driven H2 production, Chem. Commun., 2013, 49, 627–629.

100. Zhongyi Li, Yuxian Wang, Jiang Zhu, Shuqin Liu, Gang Xin, Jianjun Zhang, Heqing Huang* and Chunying Duan*, Three Series of 3d–4f Heterometallic Polymers Based on [LnCu6] or [Ln6Cu24] Clusters and Formate Bridges: Displaying Significant Magnetocaloric Effect, Crystal Growth & Design., 2013, 8, 3429–3437.

99. Zhongyi Li, Heqing Huang, Long Xu, Ruibin Liu, Jianjun Zhang, ShuQin Liu* and Chunying Duan*, 3d–4d–4f Heterotrimetallic 3D Chiral Frameworks Based on Octahedral {Ni6Ag8S12Cl} or Trigonal Dipyramidal {Co2Ag3S6} Clusters: Synthesis, Crystal Structures, and Characterization, Crystal Growth & Design., 2013, 13, 918–925.

98. Zhongyi Li, Jiang Zhu, Xiaoqun Wang, Jun Ni, Jianjun Zhang*, Shuqin Liu and Chunying Duan*, New 3d–4f heterometallic clusters built from mixed glycine and iminodiacetate acid: dioctahedron {La2Ni9} and onion-like {Gd5}⊂{Ni12} with interesting magnetocaloric effect, Dalton Trans., 2013, 42, 5711–5717.

97. Jichuan Kong, Tao Liu, Yongming Bao, Kun Jin, Xiaolin Zhang, Qin Tang, Chunying Duan*, Naphthyridine-based lanthanide complexes worked as magnetic resonance imaging contrast for guanosine 5′-monophosphate in vivo, Talanta, 2013, 117, 412–418.

96. Wenting Zhu, Xiao Wu, Cheng He, Chunying Duan*, Proline adducts of metallo-organic, sextuply-stranded lanterns as homogeneous catalysts for asymmetric catalysis, Tetrahedron, 2013, 69, 10477–10481.

95. Da-Peng Dong, Tao Liu,* Shinji Kanegawa, Soonchul Kang, Osamu Sato,* Cheng He, and Chun-Ying Duan*, Photoswitchable Dynamic Magnetic Relaxation in a Well-Isolated {Fe2Co} Double-Zigzag Chain**, Angew. Chem. Int. Ed., 2012, 51, 5119–5123.

94. Tao Liu,* Da-Peng Dong, Shinji Kanegawa, Soonchul Kang, Osamu Sato,* Yoshihito Shiota, Kazunari Yoshizawa, Shinya Hayami, Shuo Wu, Cheng He, and Chun-Ying Duan*, Reversible Electron Transfer in a Linear {Fe2Co} Trinuclear Complex Induced by Thermal Treatment and Photoirraditaion, Angew. Chem. Int. Ed., 2012, 51, 4367–4370.

93. Xu Jing, Cheng He, Dapeng Dong, Linlin Yang, and Chunying Duan*, Homochiral Crystallization of Metal–Organic Silver Frameworks: Asymmetric [32] Cycloaddition of an Azomethine Ylide, Angew. Chem. Int. Ed., 2012, 51, 10127–10131.

92. Pengyan Wu, Cheng He,* Jian Wang, Xiaojun Peng, Xuezhao Li, Yonglin An, and Chunying Duan*, Photoactive Chiral Metal-Organic Frameworks for Light-Driven Asymmetric α‑Alkylation of Aldehydes, J. Am. Chem. Soc., 2012, 134, 14991–14999.

91. Pengyan Wu , Jian Wang , Cheng He , Xiaolin Zhang , Yanting Wang , Tao Liu ,* and Chunying Duan*, Luminescent Metal-Organic Frameworks for Selectively Sensing Nitric Oxide in an Aqueous Solution and in Living Cells, Adv. Funct. Mater., 2012, 22, 1698–1703.

90. Zhong Xie, Jianhua Yang,* Jinqu Wang, Ju Bai, Huimin Yin, Bing Yuan, Jinming Lu, Yan Zhang, Liang Zhou and Chunying Duan*, Deposition of chemically modified α-Al2O3 particles for high performance ZIF-8 membrane on a macroporous tube, Chem. Commun., 2012, 48, 5977–5979.

89. Cheng He, Xiao Wu, Jichuan Kong, Tao liu, Xiaolin Zhang and Chunying Duan*, A hexanuclear gadolinium–organic octahedron as a sensitive MRI contrast agent for selectively imaging glucosamine in aqueous media, Chem. Commun., 2012, 48, 9290–9292.

88. Cheng He, Jian Wang, Pengyan Wu, Lingyun Jia,* Ying Bai, Zhichao Zhang and Chunying Duan*, Fluorescent differentiation and quantificational detection of free tryptophan in serum within a confined metal–organic tetrahedron, Chem. Commun., 2012, 48, 11880–11882.

87. Qingtao Meng, Cheng He, Weiping Su, Xiaolin Zhang, Chunying Duan*, A new rhodamine–chitosan fluorescent material for the selective detection of Hg2 in living cells and efficient adsorption of Hg2+ in natural water, Sensors and Actuators B, 2012, 174, 312–317.

86. Xiaolin Zhang, Xu Jing, Tao Liu, Gang Han, Huaqiang Li, and Chunying Duan*, Dual-Functional Gadolinium-Based Copper(II) Probe for Selective Magnetic Resonance Imaging and Fluorescence Sensing, Inorg. Chem., 2012, 51, 2325–31.

85. Qiuxia Han, Lejie Zhang, Cheng He, Jiangyang Niu, and Chunying Duan*, Metal−Organic Frameworks with Phosphotungstate Incorporated for Hydrolytic Cleavage of a DNA-Model Phosphodiester, Inorg. Chem.,2012, 51, 5118–5127.

84. Lejie Zhang, Yuan Jian, Jian Wang, Cheng He, Xuezhao Li, Tao Liu and Chunying Duan*, Post-modification of a MOF through a fluorescent-labeling technology for the selective sensing and adsorption of Ag+ in aqueous solution, Dalton Trans., 2012, 41, 101153–10155.

83. Wenting Zhu, Cheng He, Pengyan Wu, Xiao Wu and Chunying Duan*, “Click” post-synthetic modification of metal–organic frameworks with chiral functional adduct for heterogeneous asymmetric catalysis, Dalton Trans., 2012, 41, 3072–3077.

82. Qingtao Meng, Weiping Su, Cheng He, Chunying Duan *, Novel chitosan-based fluorescent materials for the selective detection and adsorption of Fe3in water and consequent bio-imaging applications, Talanta, 2012, 97, 456–461.

81. Xiaoyue Hu, Xiaolin Zhang, Honglei Song, Cheng He, Yongming Bao*, Qin Tang, Chunying Duan*, A novel copper(Ⅱ) complex-based fluorescence probe for nitric oxide detecting and imaging, Tetrahedron, 2012, 68, 8371–8375.

80. Jian Wang, Cheng He,* Pengyan Wu, Jing Wang, and Chunying Duan*, An Amide-Containing Metal-Organic Tetrahedron Responding to a Spin-Trapping Reaction in a Fluorescent Enhancement Manner for Biological Imaging of NO in Living Cells, J. Am. Chem. Soc., 2011, 133, 12402–12405.

79. Pengyan Wu, Jian Wang, Yaming Li,* Cheng He, Zhong Xie, and Chunying Duan*, Luminescent Sensing and Catalytic Performances of a Multifunctional Lanthanide-Organic Framework Comprising a Triphenylamine Moiety, Adv. Funct. Mater., 2011, 21, 2788–2794.

78. Xiao Wu, Cheng He, Xiang Wu, Siyi Qu and Chunying Duan*, An L-proline functionalized metallo-organic triangle as size-selective homogeneous catalyst for asymmetry catalyzing aldol reactions, Chem. Commun., 2011, 47, 8415–8417.

77. Xiaoyue Hu, Jian Wang, Xiang Zhu, Dapeng Dong, Xiaolin Zhang, Shuo Wu and Chunying Duan*, A copper(II) rhodamine complex with a tripodal ligand as a highly selective fluorescence imaging agent for nitric oxide, Chem. Commun., 2011, 47, 11507–11509.

76. Xiaolin Zhang, Yang Jiao, Xu Jing, Hongmei Wu, Guangjie He and Chunying Duan*. pH-sensitive fluorescent sensors based on europium(III) complexes, Dalton Trans., 2011, 40, 2522–2527.

75. Xiaoyue Hu, Xiaolin Zhang, Guangjie He, Cheng He, Chunying Duan*, A FRET approach for luminescence sensing Cr3 in aqueous solution and living cells through functionalizing glutathione and glucose moieties, Tetrahedron, 2011, 67, 1091–1095.

74. Chunying Duan,* Meilin Wei, Dong Guo, Cheng He, and Qingjin Meng, Crystal Structures and Properties of Large Protonated Water Clusters Encapsulated by Metal-Organic Frameworks, J. Am. Chem. Soc., 2010, 132, 3321–3330.

73. Dongbin Dang, Pengyan Wu, Cheng He, Zhong Xie, and Chunying Duan*, Homochiral Metal-Organic Frameworks for Heterogeneous Asymmetric Catalysis, J. Am. Chem. Soc., 2010, 132, 14321–14323.

72. Qingtao Meng, Xiaolin Zhang, Cheng He, Guangjie He, Peng Zhou, and Chunying Duan*, Multifunctional Mesoporous Silica Material Used for Detection and Adsorption of Cu2R in Aqueous Solution and Biological Applications in vitro and in vivo, Adv. Funct. Mater., 2010, 20, 1903–1909.

71. Yang Liu, Rong Zhang, Cheng He,* Dongbin Dang and Chunying Duan*, A palladium(II) triangle as building blocks of microporous molecular materials: structures and catalytic performance, Chem. Commun., 2010, 46, 746–748.

70. Dehui Wang, Bingguang Zhang,* Cheng He, Pengyan Wu and Chunying Duan*, A new chiral N-heterocyclic carbene silver(I) cylinder: synthesis,crystal structure and catalytic properties, Chem. Commun., 2010, 46, 4728–4730.

69. Dongbin Dang, Yan Bai, Cheng He, Jian Wang, Chunying Duan,* and Jingyang Niu, Structural and Catalytic Performance of a Polyoxometalate-Based Metal-Organic Framework Having a Lanthanide Nanocage as a Secondary Building Block, Inorg. Chem., 2010, 49, 1280–1282.

68. Yang Liu, Zhihua Lin, Cheng He*, Liang Zhao and Chunying Duan*, A symmetry-controlled and face-driven approach for the assembly of cerium-based molecular polyhedral, Dalton Trans., 2010, 39, 11122–11125.

67. Yang Liu, Xiao Wu, Cheng He*, Zhongyi Li and Chunying Duan*, Metal–organic polyhedra for selective sensing of ribonucleosides through the cooperation of hydrogen-bonding interactions, Dalton Trans., 2010, 39, 7727–7732.

66. Xiang Zhu, Cheng He*, Dapeng Dong, Yang Liu and Chunying Duan*, Cerium-based triple-stranded helicates as luminescent chemosensors for the selective sensing of magnesium ions, Dalton Trans., 2010, 39, 10051–10055.

65. Dehui Wang, Xiaolin Zhang, Cheng He and Chunying Duan*, Aminonaphthalimide-based imidazolium podands for turn-on fluorescence sensing of nucleoside polyphosphates, Org. Biomol. Chem., 2010, 8, 2923–2925.

64. Guangjie He, Xiaolin Zhang*, Cheng He, Xiuwen Zhao, Chunying Duan*, Ratiometric fluorescence chemosensors for copper(II) and mercury(II) based on FRET systems, Tetrahedron, 2010, 66, 9762–9768.

63. Guangjie He, Dong Guo, Cheng He, Xiaolin Zhang, Xiuwen Zhao, and Chunying Duan*, A Color-Tunable Europium Complex Emitting Three Primary Colors and White Light, Angew. Chem. Int. Ed., 2009, 48, 6132–6135.

62. Hongmei Wu, Cheng He,* Zhihua Lin, Yang Liu, and Chunying Duan*, Metallohelical Triangles for Selective Detection of Adenosine Triphosphate in Aqueous Media, Inorg. Chem., 2009, 48, 408–410.

61. Wei Huang, Chunxia Song, Cheng He,* Guojun Lv, Xiaoyue Hu, Xiang Zhu, and Chunying Duan*, Recognition Preference of Rhodamine-Thiospirolactams for Mercury(II) in Aqueous Solution, Inorg. Chem., 2009, 48, 5061–5072.

60. Dayu Wu, Dong Guo, You Song, Wei Huang, Chunying Duan,* Qingjin Meng, and Osamu Sato, CoII Molecular Square with Single-Molecule Magnet Properties, Inorg. Chem., 2009, 48, 854–860.

59. Wei Huang, Dayu Wu, Peng Zhou, Wenbo Yan, Dong Guo, Chunying Duan* and Qingjin Meng*, Luminescent and Magnetic Properties of Lanthanide-Thiophene-2,5-dicarboxylate Hybrid Materials, Crystal Growth & Design., 2009, 9, 1361–1369.

58. Wei Huang, Dayu Wu, Dong Guo, Xiang Zhu, Cheng He*, Qingjin Meng and Chunying Duan*, Efficient near-infrared emission of a Ytterbium(III) compound with a green light rhodamine donor, Dalton Trans., 2009, 12, 2081–2084.

57. Wei Huang, Xiang Zhu, Dayu Wu, Cheng He*, Xiaoyue Hu and Chunying Duan*, Structural modification of rhodamine-based sensors toward highly selective mercury detection in mixed organic/aqueous media, Dalton Trans., 2009, 47, 10457–10465.

56. Hui Zhang, Lixia Xie, Wenbo Yan, Cheng He,* Xin Cao and Chunying Duan*, Conformational switching fluorescent chemodosimeter for the selective detection of silver(I) ions, New J. Chem., 2009, 33, 1478–1481.

55. Hongmei Wu, Peng Zhou,* Jian Wang, Liang Zhao and Chunying Duan*, Dansyl-based fluorescent chemosensors for selective responses of Cr(III), New J. Chem., 2009, 33, 653–658.

54. Wei Huang, Peng Zhou, Wenbo Yan, Cheng He, Liqin Xiong, Fuyou Li* and Chunying Duan*, A bright water-compatible sugar-rhodamine fluorescence sensor for selective detection of Hg2in natural water and living cells, J. Environ. Monit., 2009, 11, 330–335.

53. Peng Zhou, Qingtao Meng, Guangjie He, Hongmei Wu, Chunying Duan* and Xie Quan, Highly sensitive fluorescence probe based on functional SBA-15 for selective detection of Hg2 in aqueous media, J. Environ. Monit., 2009, 11, 648–653.

52. Cheng He, Zhihua Lin, Zheng He, Chunying Duan,* Chunhu Xu, Zheming Wang, and Chunhua Yan, Metal-Tunable Nanocages as Artificial Chemosensors**, Angew. Chem. Int. Ed., 2008, 47, 877–881.

51. Yonggang Zhao, Dong Guo, Yang Liu, Cheng He and Chunying Duan*, A mixed-valence (FeII)2(FeIII)2 square for molecular expression of quantum cellular automata, Chem. Commun., 2008, 5725–5727.

50. Dayu Wu, Wei Huang, Zhihua Lin, Chunying Duan,* Cheng He, Shuo Wu, and Dehui Wang, Highly Sensitive Multiresponsive Chemosensor for Selective Detection of Hg2in Natural Water and Different Monitoring Environments, Inorg. Chem., 2008, 47, 7190–7201.

49. Guangjie He, Yonggang Zhao, Cheng He,* Yang Liu, and Chunying Duan*, “Turn-On” Fluorescent Sensor for Hg2via Displacement Approach, Inorg. Chem., 2008, 47, 5169–5176.

48. Yang Liu, Xiao Wu, Cheng He*, Rong Zhang and Chunying Duan*, A truncated octahedral nanocage for fluorescent detection of nucleoside, Dalton Trans., 2008, 43, 5866–5868.

47. Cheng He, Bingguang Zhang, Lixia Xie, Yang Liu and Chunying Duan*, Stereoselective association of ferrocene-contained molecular clips incoordination polymers, CrystEngComm., 2008, 10, 759–764.

46. Cheng He, Yonggang Zhao, Dong Guo*, Zhihua Lin and Chunying Duan*, Chirality Transfer through Helical Motifs in Coordination Compounds, Inorg. Chem., 2007, 22, 3451–3463.

45. Dayu Wu, Wei Huang, Chunying Duan,* Zhihua Lin, and Qingjin Meng, Highly Sensitive Fluorescent Probe for Selective Detection of Hg2 in DMF Aqueous Media, Inorg. Chem., 2007, 46, 1538−1540.

44. Meilin Wei, Cheng He, Qiaozhen Sun, Qingjin Meng, and Chunying Duan*, Zeolite Ionic Crystals Assembled through Direct Incorporation of Polyoxometalate Clusters within 3D Metal−Organic Frameworks, Inorg. Chem., 2007, 46, 5957−5966.

43. Qiaozhen Sun, Meilin Wei, Yan Bai, Cheng He*, Qingjin Meng and Chunying Duan*, Entanglement of individual coordination polymers having helicates as building intermediates, Dalton Trans., 2007, 36, 4089–4094.

42. Dayu Wu, Wei Huang, Weijie Hua, You Song, Chunying Duan*, ShuHua Li and QingJin Meng, Metal complexes formed by metal-assisted solvolysis of di-pyridylketone azine: structures and magnetic properties, Dalton Trans., 2007, 18, 1838–1845.

41. Zhi-hua Lin, Li-xia Xie, Yong-gang Zhao, Chun-ying Duan* and Jing-ping Qu*, Thiourea-based molecular clips for fluorescent discrimination of isomeric dicarboxylates, Org. Biomol. Chem., 2007, 5, 3535–3538.

40. Meilin Wei, Cheng He, Weijie Hua, Chunying Duan,* Shuhua Li, and Qingjin Meng*, A Large Protonated Water Cluster H+(H2O)27 in a 3D Metal-Organic Framework, J. Am. Chem. Soc., 2006, 128, 13318–13319.

39. Zhi-hua Lin, Sheng-ju Ou, Chun-ying Duan,* Bing-guang Zhang and Zhi-ping Bai*, Naked-eye detection of fluoride ion in water: a remarkably selective easy-to-prepare test paper, Chem. Commun., 2006, 624–626.

38. Yan Bai, Guang-jie He, Yong-gang Zhao, Chun-ying Duan,* Dong-bin Dang and Qing-jin Meng*, Porous material for absorption and luminescent detection of aromatic molecules in water, Chem. Commun., 2006, 1530–1532.

37. Qiaozhen Sun, Yan Bai, Guangjie He, Chunying Duan,* Zhihua Lin and Qingjin Meng*, Spontaneous resolution of silver double helicates consisting of achiral ligands with several aromatic rings, Chem. Commun., 2006, 2777–2779.

36. Shengju Ou, Zhihua Lin, Chunying Duan,* Haitao Zhang and Zhiping Bai*, A sugar-quinoline fluorescent chemosensor for selective detection of Hg2+ ion in natural water, Chem. Commun., 2006, 4392–4394.

35. Yonggang Zhao, Zhihua Lin, Cheng He,* Hongmei Wu, and Chunying Duan*, A “Turn-On” Fluorescent Sensor for Selective Hg(II) Detection in Aqueous Media Based on Metal-Induced Dye Formation, Inorg. Chem., 2006, 45, 10013−10015.

34. Mingxue Li, Qiaozhen Sun, Yan Bai, Chunying Duan*, Bingguang Zhang and Qingjin Meng, Chiral aggregation and spontaneous resolution of thiosemicarbazone metal complexes, Dalton Trans., 2006, 21, 2572–2578.

33. Zhihua Lin, Yonggang Zhao, Chunying Duan*, Bingguang Zhang and Zhiping Bai*, A highly selective chromo- and fluorogenic dual responding fluoride sensor: naked-eye detection of F− ion in natural water via a test paper, Dalton Trans., 2006, 30, 3678–3684.

32. Dayu Wu, Lixia Xie, Changli Zhang, Chunying Duan*, Yonggang Zhao and Zijian Guo*, Quinoline-based molecular clips for selective fluorescent detection of Zn2+, Dalton Trans., 2006, 29, 3528–3533.

31. Bingguang Zhang, Jian Xu, Yonggang Zhao, Chunying Duan*, Xin Cao and Qingjin Meng, Host–guest complexation of a fluorescent and electrochemical chemsensor for fluoride anion, Dalton Trans., 2006, 10, 1271–1276.

30. Yan Bai, Bing-Guang Zhang, Chun-Ying Duan,* Dong-Bin Dang and Qing-Jin Meng, Anion induced binding electrochemical signal transduction in ferrocenyl benzolimidazolium podands, New J. Chem., 2006, 30, 266–271.

29. Yong-gang Zhao, Bing-guang Zhang, Chun-ying Duan,* Zhi-hua Lin and Qing-jin Meng*, A highly selective fluorescent sensor for fluoride through ESPT signaling transduction, New J. Chem., 2006, 30, 1207–1213.

28. Yonggang Zhao, Zhihua Lin, Haiping Liao, Chunying Duan*, Qingjin Meng, A highly selective fluorescent chemosensor for Al3+ derivated from 8-hydroxyquinoline, Inorganic Chemistry Communications., 2006, 9, 966–968.

27. Yonggang Zhao, Zhihua Lin, Shengju Ou, Chunying Duan*, Haiping Liao, Zhiping Bai*, A highly selective Ru-based chemosensor for fluoride ion, Inorganic Chemistry Communications., 2006, 9, 802–805.

26. Yan Bai, Chunying Duan*, Ping Cai, Dongbin Dang and Qingjin Meng, Enantiomeric interpenetrating 3D nets with chiral silver helicates, Dalton Trans., 2005, 16, 2678–2680.

25. Ping Cai, Mingxue Li, Chunying Duan*, Feng Lu, and Qingjin Meng, Synthesis and Properties of the Geometrically Controlled Mixed-Valence Tetrahedral RuII2RuIII2L6 Cluster, Inorg. Chem., 2005, 13, 2581–2585.

24. Mingxue Li, Yan Bai, Bingguang Zhang, Chunying Duan,* Jian Xu, and Qingjin Meng*, Heterometallic Compounds Assembled from Ferrocene-Containing Bisthiosemicarbazone Clips, Inorg. Chem., 2005, 44, 5459−5466.

23. Yan Bai, Dongbin Dang, Chunying Duan,* You Song, and Qingjin Meng*, Synthesis and Structural Characterization of a Nonplanar Neutral [36] Metallacrown-12 Nickel Compound [Ni(C13H9N3O2)(CH3OH)]12, Inorg. Chem., 2005, 44, 5972−5974.

22. Ping Cai, Ming-xue Li, Chun-Ying Duan,* Feng Lu, Dong Guo and Qing-Jin Meng, Syntheses, crystal structure and electrochemical properties of dinuclear ruthenium complexes containing saturated and unsaturated spacersw, New J. Chem., 2005, 29, 1011–1016.

21. Yan Bai, Bing-Guang Zhang, Jian Xu, Chun-Ying Duan,* Dong-Bin Dang, De-Jun Liu and Qing-Jin Meng*, Conformational switching fluorescent chemosensor for chloride anion, New J. Chem., 2005, 29 , 777–779.

20. Yan Bai, Dong Guo, Chun-ying Duan,* Dong-bin Dang, Ke-liang Pang and Qing-jin Meng*, A three dimensional porous metal–organic framework [Fe4L6·(DMF) 3·(H2O)10] constructed from neutral discrete Fe4L6 pyramids [H2L = 1,3-benzodihydroxamix acid], Chem. Commun., 2004 , 186–187.

19. Dong Guo, Chun-ying Duan,* Feng Lu, Yasuchika Hasegawa, Qing-jin Meng and Shozo Yanagida*, Lanthanide heterometallic molecular squares Ru2–Ln2 exhibiting sensitized near-infrared emission, Chem. Commun., 2004 ,1486 –1487.

18. Bing-guang Zhang, Ping Cai, Chun-ying Duan,* Ren Miao, Long-gen Zhu, Takashi Niitsu* and Hakuai Inoue, Imidazolidinium-based robust crypt with unique selectivity for fluoride anion, Chem. Commun., 2004 ,2206–2207.

17. Mingxue Li, Ping Cai, Chunying Duan,* Feng Lu, Jin Xie, and Qingjin Meng*, Octanuclear Metallocyclic Ni4Fc4 Compound: Synthesis, Crystal Structure, and Electrochemical Sensing for Mg2+, Inorg. Chem., 2004, 43, 5174−5176.

16. Zheng He, Cheng He, ZheMing Wang*, EnQing Gao, Yuan Liu and ChunHua Yan*, Self-assembly of molecular squares based on easy-to-prepare multidentate Schiff base ligands, Dalton Trans., 2004, 129, 502–504.

15. Zhang Bing-guang, Guo Dong, Duan Chun-ying,* Cai Ping and Meng Qing-jin*, A novel pyramidal multiple alkali metal cluster [K3(H2O)]3 stabilized within a capsule containing 16-nitrogen donors, Chem. Commun., 2003, 1836–1837.

14. Dong Guo, Chunqi Qian, Chunying Duan*, Keliang Pang, and Qingjin Meng*, Synthesis and Structural Characterization of a Novel Mixed-Valent CuIICuICuII Triangular Metallomacrocycle Using an Imine-Based Rigid Ligand, Inorg. Chem., 2003, 42, 2024–2030.

13. Dong Guo, Yuting Li, Chun-ying Duan*, Hong Mo, and Qingjin Meng*, Heterodimetallic Compounds Assembled from Ferrocenedicarboxylato and Ferrocenecarboxylato Ligands, Inorg. Chem., 2003, 42, 2519−2530.

12. Keliang Pang, Dong Guo, Chunying Duan*, Hong Mo, and Qingjin Meng*, Generation of an Equilibrating Collection of Crystalline Solids from a Dynamic Combinational Library, Inorg. Chem., 2003, 42, 5453−5455.

11. Dong Guo, Bingguang Zhang, Chunying Duan*, Xin Cao and Qingjin Meng*, A novel ferrocene–barium sandwich sheet-shaped coordination polymer and its solid-state electrochemistry, Dalton Trans., 2003, 127, 282–284.

10. Hong Mo, Chenjie Fang, Chunying Duan*, Yuting Li and Qingjin Meng*, Crystal structures of metal–organic frameworks sustained by π–π interactions between triple-helices, Dalton Trans., 2003, 128, 1229–1234.

9. Guo Dong, Han Gang, Duan Chunying,* Pang Ke-liang and Meng Qingjin*, Novel ferrocene-containing helical triangular macrocycle achieved via an exchange reaction, Chem. Commun., 2002, 1096–1097.

8. Dong Guo, Ke liang Pang, Chunying Duan*, He Cheng, and Qingjin Meng*, Design and Crystal Structures of Triple Helicates with Crystallographic Idealized D3 Symmetry: The Role of Side Chain Effect on Crystal Packing, Inorg. Chem., 2002, 41, 5978–5985.

7. Dong Guo, Hong Mo, Chunying Duan, Feng Lu* and Qingjin Meng*, Novel ferrocene-based mixed-metal coordination polymers, Dalton Trans., 2002, 13, 2593–2594.

6. Guo Dong, He Cheng, Duan Chunying,* Qian Chunqi and Meng Qingjin*, The synthesis and structural characterisation of helical silver(I) complexes with short bis(pyridylimine) ligands, New J. Chem., 2002, 26, 796–802.

5. Fang Chen-jie, Duan Chun-ying,* Guo Dong, He Cheng, Meng Qing-jin,* Wang Zhe-ming and Yan Chun-hua, Self-assembly of a chloro-bridged helical coordination polymer achieved from a ferrocenyl-containing double-helicate, Chem. Commun., 2001, 2540–2541.

4. Zhang Bing-guang, Mo Hong Duan Chun-ying,* He Cheng, Meng Qing-jin, Wang Zhe-ming and Yan Chun-hua, Novel highly symmetrical cube-shaped cation with 16-nitrogen donors, Chem. Commun., 2001, 2652–2653.

3. Fang Chen-jie, Duan Chun-ying,* He Cheng and Meng Qing-jin*, A double-helix generated from a ferrocenyl-thiosemicarbazato metallo-synthon and its novel hydrogen-bonding cavities, Chem. Commun., 2000, 1187–1188.

2. Fang Chen-jie, Duan Chun-ying,* He Cheng, Han Gang and Meng Qing-jin*, A supramolecular analog of cyclohexane sustained by aromatic C–H…π interactions between ferrocene moieties : molecular packing of ferrocene-containing thiosemicarbazato metal complexes, New J. Chem., 2000, 24, 697–701.

1. Chun-ying Duan,* Ze-hua Liu, Xiao-zeng You, Feng Xue and Thomas C. W. Mak*, A self-assembled macrocyclic tetranuclear molecular square [Co(HL)] 44+ [H2L = tetra(2-pyridyl)thiocarbazone], Chem. Commun., 1997, 381–382.

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